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- W2087604792 abstract "Aqueous reaction of ammonium thiosulfate with piperazine (pip) results in the formation of the title compound (pipH2)[S2O3]∙H2O 1 (pipH2 = piperazinediium) in good yield. 1 was characterized by elemental analysis, IR, Raman and NMR spectra, X-ray powder pattern and its structure was determined. On heating at 100°C, 1 transforms to anhydrous piperazinediium thiosulfate 2, which can be rehydrated to the monohydrate on exposure to moisture. The structure of 1 consists of two crystallographically independent piperazinediium (pipH2)2+ cations located on inversion centers, a thiosulfate anion and a lattice water. The organic cations, thiosulfate anion and lattice water are linked by six varieties of hydrogen bond namely O–H∙∙∙O, O–H∙∙∙S, N–H∙∙∙O, N–H∙∙∙S, C–H∙∙∙O and C–H∙∙∙S, leading to the formation of alternating layers of (pipH2)2+ cations and water linked thiosulfate chains. A comparative study of several compounds charge balanced by the piperazinediium cation is described. The synthesis, properties and supramolecular structure of piperazinediium thiosulfate monohydrate are described." @default.
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- W2087604792 date "2011-01-01" @default.
- W2087604792 modified "2023-09-24" @default.
- W2087604792 title "Synthesis, properties and supramolecular structure of piperazinediium thiosulfate monohydrate+" @default.
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- W2087604792 doi "https://doi.org/10.1007/s12039-011-0064-9" @default.
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