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- W2087617810 abstract "The synthesis of the chiral ligand (R,R)-BIPHOP-F is detailed. Its coordination to a cationic cyclopentadienyl ruthenium fragment generates [Ru (acetone)(R,R)-BIPHOP-F)Cp][SbF6], a transition metal Lewis acid that catalyzes the [3+2] dipolar cycloaddition reaction between aryl nitrile oxides and α,β-unsaturated aldehydes to give chiral 2-isoxazolines with yields of 43–98% and asymmetric purity of 60–93% ee. The stereochemistry of the major enantiomer is S, consistent with an approach of the nitrile oxide to the Cα-Si face of the enal in the anti-s-trans conformation in the catalyst site." @default.
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- W2087617810 date "2007-08-01" @default.
- W2087617810 modified "2023-10-10" @default.
- W2087617810 title "Chiral ruthenium Lewis acid-catalyzed nitrile oxide cycloadditions" @default.
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- W2087617810 doi "https://doi.org/10.1016/j.tet.2007.06.033" @default.
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