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• W2087661789 endingPage "14485" @default.
• W2087661789 startingPage "14478" @default.
• W2087661789 abstract "The reaction occurring on electrooxidation of Ru(bpy)32+ (bpy = 2,2‘-bipyridine) and tri-n-propylamine (TPrA) leads to the production of Ru(bpy)32+* and light emission. The accepted mechanism of this widely used reaction involves the reaction of Ru(bpy)33+ and a reduced species derived from the free radical of the TPrA. However, this mechanism does not account for many of the observed features of this reaction. A new route involving the intermediacy of TPrA cation radicals (TPrA•+) in the generation of Ru(bpy)32+* was established, based on results of scanning electrochemical microscopy (SECM)-electrogenerated chemiluminescence (ECL) experiments, as well as cyclic voltammetry simulations. A half-life of ∼0.2 ms was estimated for TPrA•+ in neutral aqueous solution. Direct evidence for TPrA•+ in this medium was obtained via flow cell electron spin resonance (ESR) experiments at ∼20 °C. The ESR spectra of the TPrA•+ species consisted of a relatively intense and sharp septet with a splitting of ∼20 G and a g value of 2.0038." @default.
• W2087661789 created "2016-06-24" @default.
• W2087661789 creator A5005657217 @default.
• W2087661789 creator A5080906459 @default.
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• W2087661789 date "2002-11-09" @default.
• W2087661789 modified "2023-10-18" @default.
• W2087661789 title "Electrogenerated Chemiluminescence 69: The Tris(2,2‘-bipyridine)ruthenium(II), (Ru(bpy)₃²⁺)/Tri-<i>n</i>-propylamine (TPrA) System RevisitedA New Route Involving TPrA^•+ Cation Radicals" @default.
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• W2087661789 doi "https://doi.org/10.1021/ja027532v" @default.
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• W2087661789 hasPublicationYear "2002" @default.
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