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- W2087662279 abstract "Surface pressure (Π) vs surface area (A) isotherms of dihexadecyl phosphate (DHP) monolayers floating on aqueous tris(2,2‘-bipyridyl)ruthenium(II) chloride ([Ru(bpy)3][Cl2]) solutions have established the formation of liquid expanded (LE), liquid condensed (LC), and solid condensed (SC) phases. Repeated compression and expansion cycles lead to the irreversible formation of a SC phase. Horizontal lifting of a hydrophilic substrate through the monolayer resulted in the transfer of a layer of DHP-coated [Ru(bpy)3]2+ microcrystallites. Additional layers of DHP/[Ru(bpy)3]2+ micocrystallites have been transferred by Schaefer's method. The presence of [Ru(bpy)3]2+ microcrystallites in the transferred multilayers has been established by absorption and fluorescence spectroscopies. The absorption and emission spectra of [Ru(bpy)3]2+ microcrystallites, grown under the DHP monolayers, had their maxima red-shifted and blue-shifted with respect to those observed for [Ru(bpy)3][Cl2] in aqueous solution. Near-field scanning optical microscopy (NSOM) has been employed to spatially and spectrally resolve, at a submicron resolution, the presence of isolated seed crystals and their growth into differently shaped [Ru(bpy)3]2+ microcrystallites. NSOM also provided information on domain boundaries and on the partitioning of the fluorescent species into the various phases in the monolayer. Site-resolved near-field fluorescence spectroscopy provided evidence for the presence of [Ru(bpy)3]2+ microcrystallites in the circular domains formed under a DHP monolayer." @default.
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- W2087662279 date "1999-08-31" @default.
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- W2087662279 title "Dihexadecyl Phosphate Monolayer Supported [Ru(bpy)<sub>3</sub>]<sup>2+</sup> Crystallites Investigated by Near-Field Scanning Optical Microscopy" @default.
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- W2087662279 doi "https://doi.org/10.1021/jp990687d" @default.
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