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- W2087663605 abstract "This is a survey of the preparation and structural properties of the intermetallic phases of gallium and alkali metals. Unlike the already known phases of gallium with lithium or sodium, the structures of the recently discovered phases Li3Ga14, Na22Ga39, KGa3, K3Ga13, RbGa3, RbGa7, and CsGa7 are characterized by stackings of coordinated gallium polyhedra such as icosahedra, octadecahedra, dodecahedra, and undecahedra. In these phases the alkali metals stabilize the gallium framework by giving their valence electrons. On this basis, the structures are interpreted according to Wade's electron-counting procedure, bringing the Zintl phases to a more general concept and enhancing the interest on the transition forms between metallic and ionic bonding." @default.
- W2087663605 created "2016-06-24" @default.
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- W2087663605 date "1983-06-01" @default.
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- W2087663605 title "The intermetallic phases of gallium and alkali metals. Interpretation of the structures according to Wade's electron-counting methods" @default.
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- W2087663605 doi "https://doi.org/10.1016/0022-4596(83)90057-9" @default.
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