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- W2087664025 abstract "The effects of solvents and added salts on the triethyl phosphite catalysed anionic polymerization of acrylonitrile are described. The initial rate of polymerization increased but the degree of polymerization decreased with increase in polarity of solvent, except for hexane and dimethylformamide. Tetraethyl ammonium bromide increased the rate of polymerization, probably due to exchange of the counter-cation between tetraethyl ammonium cation and the phosphonium cation. Addition of tetraethyl ammonium bromide also decreased the order with respect to the monomer for polymerization in acetonitrile. The polymerization in dimethylformamide was found to be approximately second order with respect to the monomer, independently of the added ions." @default.
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- W2087664025 date "1977-01-01" @default.
- W2087664025 modified "2023-10-15" @default.
- W2087664025 title "Effects of trivalent phosphorus compounds on vinyl polymerizations—V. Effects of solvents and tetraethylammonium bromide on the anionic polymerization of acrylonitrile initiated by triethyl phosphite" @default.
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- W2087664025 doi "https://doi.org/10.1016/0014-3057(77)90107-0" @default.
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