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- W2087667020 abstract "An efficient synthetic pathway for the synthesis of biscalix[4]arenes 5-10 using 1,3-dipolar cycloaddition reactions is reported. Biscalix[4]arene 10 is capable of forming a complex with methyl viologen because of favorable cation-π interactions and a proper cavity size to accommodate the guest. Moreover, biscalix[4]arenes 8a and 8b were found to be atropisomers at room temperature. These two conformers were unable to exchange at room temperature because of the restricted rotation of the C(9)-C(11) or C(10)-C(12) bonds of the β-amino-α,β-unsaturated ketones of anthracene." @default.
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- W2087667020 date "2012-02-21" @default.
- W2087667020 modified "2023-09-27" @default.
- W2087667020 title "Synthesis of 9,10-Bis-ketoenaminoanthryl and 9,10-Bis-isoxazolylanthryl Linked Biscalix[4]arenes: Atropisomers and Molecular Recognitions" @default.
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- W2087667020 doi "https://doi.org/10.1021/jo2024784" @default.
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