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• W2087684737 endingPage "9790" @default.
• W2087684737 startingPage "9781" @default.
• W2087684737 abstract "Ring-closing metathesis (RCM) strategies toward the synthesis of a number of constrained sulfamides are discussed. This approach exploits the inherent chemistry of sulfamides and sulfonyl carbamates to generate both symmetric and unsymmetric cyclic sulfamides. Two strategies are revealed, one centers on the RCM reaction of allylated sulfamides 9a–e to generate the C2-symmetric cyclic sulfamides 4a–e in high yields. A second RCM strategy utilizes the known sulfonyl carbamate 15 to prepare unsymmetric cyclic sulfamides 16 and 6 in two four-step sequences. Overall, the routes described are applicable to the synthesis of a variety of constrained dipeptidal sulfamides representing novel peptidomimetic scaffolds." @default.
• W2087684737 created "2016-06-24" @default.
• W2087684737 creator A5004065846 @default.
• W2087684737 creator A5026618774 @default.
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• W2087684737 creator A5041013334 @default.
• W2087684737 creator A5054923752 @default.
• W2087684737 creator A5070428204 @default.
• W2087684737 creator A5090540786 @default.
• W2087684737 date "2000-12-01" @default.
• W2087684737 modified "2023-10-09" @default.
• W2087684737 title "Ring-Closing Metathesis Strategies to Cyclic Sulfamide Peptidomimetics" @default.
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• W2087684737 doi "https://doi.org/10.1016/s0040-4020(00)00885-1" @default.

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