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• W2087702016 abstract "Abstract Salt‐like hydrated complexes of formulae Na[Py 8 TPyzPzCo] and [Py 8 TPyzPzCo](SbCl 6 ) containing Co I and Co III , respectively, and the neutral Co II –bis(dimethyl sulfoxide) (DMSO) adduct [Py 8 TPyzPzCo(DMSO) 2 ], bearing additional clathrated DMSO molecules, have been prepared and characterized {Py 8 TPyzPz = tetrakis[5,6‐di(2‐pyridyl)‐2,3‐pyrazino]porphyrazinato dianion}. The sodium Co I salt, the anion of which, [Py 8 TPyzPzCo] 1– , had previously been identified by electrochemical solution studies, represents the first example of a Co I derivative of a tetrapyrrolic macrocyclic chromophore prepared as a solid pure material. Solutions of Na[Py 8 TPyzPzCo] in DMSO, under defined experimental conditions, allow the slow formation (months) of crystals of its corresponding Co II complex of formula [Py 8 TPyzPzCo(DMSO) 2 ] · 6 DMSO. The structure of the adduct, elucidated by single‐crystal X‐ray analysis, shows the central Co II ion surrounded by the four pyrrole N atoms of the porphyrazine macrocycle and two O atoms of the axially bonded DMSO molecules. Oxidation of the basic starting material [Py 8 TPyzPzCo] with phenoxathiin hexachloroantimonate (phenox‐SbCl 6 ) led to the formation of the Co III complex [Py 8 TPyzPzCo](SbCl 6 ). Full characterization of the title Co I , Co II , and Co III species has been accomplished by solution studies and from IR, UV/Vis, EPR and X‐ray crystallography data.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)" @default.
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• W2087702016 date "2009-04-01" @default.
• W2087702016 modified "2023-10-03" @default.
• W2087702016 title "Redox Chemistry of Tetrakis[5,6‐di(2‐pyridyl)‐2,3‐pyrazino]porphyrazinatocobalt(II): Isolation and Characterization of Solid Pure Co^I, Co^II, and Co^III Complexes" @default.
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• W2087702016 doi "https://doi.org/10.1002/ejic.200900029" @default.
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