Matches in SemOpenAlex for { <https://semopenalex.org/work/W2087721997> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W2087721997 endingPage "395" @default.
- W2087721997 startingPage "393" @default.
- W2087721997 abstract "The technique of laser flash photolysis has been used to set limits on the rate constants for the bimolecular reactions of SiH2 with methane (CH4) and tetramethylsilane (SiMe4) at both ambient and elevated temperatures (ca 600 K). These limits show that the energy barriers to insertion reactions of SiH2 in the CH bonds of CH4 are at least 45(±6) kJ mol−1 and in the CH and/or SiC bonds of SiMe4 are at least 23(±6) kJ mol−1. The best thermochemical estimate of the activation energy for SiH2+CH4 is 59(±12) kJ mol−1. Reasons for the greatly diminished reactivity of SiH2 with CH as compared with SiH bonds are discussed. © 1999 John Wiley & Sons, Inc. Int J Chem Kinet 31: 393–395, 1999" @default.
- W2087721997 created "2016-06-24" @default.
- W2087721997 creator A5068653815 @default.
- W2087721997 creator A5087515504 @default.
- W2087721997 date "1999-01-01" @default.
- W2087721997 modified "2023-09-26" @default.
- W2087721997 title "Communication:The insertion of silylene in C?H bonds; rate constant limits and the energy barrier" @default.
- W2087721997 cites W1966372344 @default.
- W2087721997 cites W1968059478 @default.
- W2087721997 cites W1992902787 @default.
- W2087721997 cites W1994512628 @default.
- W2087721997 cites W1996095974 @default.
- W2087721997 cites W2010559684 @default.
- W2087721997 cites W2018484920 @default.
- W2087721997 cites W2033318476 @default.
- W2087721997 cites W2038580467 @default.
- W2087721997 cites W2039099844 @default.
- W2087721997 cites W2041917097 @default.
- W2087721997 cites W2042893568 @default.
- W2087721997 cites W2054927327 @default.
- W2087721997 cites W2056907509 @default.
- W2087721997 cites W2069493068 @default.
- W2087721997 cites W2087946697 @default.
- W2087721997 cites W2096101993 @default.
- W2087721997 cites W2241127975 @default.
- W2087721997 cites W2950715798 @default.
- W2087721997 cites W2952791253 @default.
- W2087721997 cites W4206829017 @default.
- W2087721997 doi "https://doi.org/10.1002/(sici)1097-4601(1999)31:5<393::aid-kin9>3.0.co;2-2" @default.
- W2087721997 hasPublicationYear "1999" @default.
- W2087721997 type Work @default.
- W2087721997 sameAs 2087721997 @default.
- W2087721997 citedByCount "16" @default.
- W2087721997 countsByYear W20877219972013 @default.
- W2087721997 countsByYear W20877219972019 @default.
- W2087721997 crossrefType "journal-article" @default.
- W2087721997 hasAuthorship W2087721997A5068653815 @default.
- W2087721997 hasAuthorship W2087721997A5087515504 @default.
- W2087721997 hasConcept C121332964 @default.
- W2087721997 hasConcept C122032599 @default.
- W2087721997 hasConcept C13472781 @default.
- W2087721997 hasConcept C142724271 @default.
- W2087721997 hasConcept C147789679 @default.
- W2087721997 hasConcept C148898269 @default.
- W2087721997 hasConcept C178790620 @default.
- W2087721997 hasConcept C185592680 @default.
- W2087721997 hasConcept C204787440 @default.
- W2087721997 hasConcept C2776758007 @default.
- W2087721997 hasConcept C2776910235 @default.
- W2087721997 hasConcept C2778200147 @default.
- W2087721997 hasConcept C32909587 @default.
- W2087721997 hasConcept C516920438 @default.
- W2087721997 hasConcept C544956773 @default.
- W2087721997 hasConcept C62520636 @default.
- W2087721997 hasConcept C71924100 @default.
- W2087721997 hasConcept C93391505 @default.
- W2087721997 hasConcept C95121573 @default.
- W2087721997 hasConceptScore W2087721997C121332964 @default.
- W2087721997 hasConceptScore W2087721997C122032599 @default.
- W2087721997 hasConceptScore W2087721997C13472781 @default.
- W2087721997 hasConceptScore W2087721997C142724271 @default.
- W2087721997 hasConceptScore W2087721997C147789679 @default.
- W2087721997 hasConceptScore W2087721997C148898269 @default.
- W2087721997 hasConceptScore W2087721997C178790620 @default.
- W2087721997 hasConceptScore W2087721997C185592680 @default.
- W2087721997 hasConceptScore W2087721997C204787440 @default.
- W2087721997 hasConceptScore W2087721997C2776758007 @default.
- W2087721997 hasConceptScore W2087721997C2776910235 @default.
- W2087721997 hasConceptScore W2087721997C2778200147 @default.
- W2087721997 hasConceptScore W2087721997C32909587 @default.
- W2087721997 hasConceptScore W2087721997C516920438 @default.
- W2087721997 hasConceptScore W2087721997C544956773 @default.
- W2087721997 hasConceptScore W2087721997C62520636 @default.
- W2087721997 hasConceptScore W2087721997C71924100 @default.
- W2087721997 hasConceptScore W2087721997C93391505 @default.
- W2087721997 hasConceptScore W2087721997C95121573 @default.
- W2087721997 hasIssue "5" @default.
- W2087721997 hasLocation W20877219971 @default.
- W2087721997 hasOpenAccess W2087721997 @default.
- W2087721997 hasPrimaryLocation W20877219971 @default.
- W2087721997 hasRelatedWork W1988569765 @default.
- W2087721997 hasRelatedWork W2003143814 @default.
- W2087721997 hasRelatedWork W2009569478 @default.
- W2087721997 hasRelatedWork W2017867868 @default.
- W2087721997 hasRelatedWork W2039604248 @default.
- W2087721997 hasRelatedWork W2057239053 @default.
- W2087721997 hasRelatedWork W2087721997 @default.
- W2087721997 hasRelatedWork W2090064364 @default.
- W2087721997 hasRelatedWork W2090933694 @default.
- W2087721997 hasRelatedWork W2155086889 @default.
- W2087721997 hasVolume "31" @default.
- W2087721997 isParatext "false" @default.
- W2087721997 isRetracted "false" @default.
- W2087721997 magId "2087721997" @default.
- W2087721997 workType "article" @default.