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- W2087724187 abstract "Oxidation properties of CeO2-ZrO2 catalysts were investigated as a function of oxidation temperature by a combination of TPR and O2 pulse injection methods. Ce3+ species formed from the CeO2 phase in the CeO2-ZrO2(5/1) catalyst and CeO2 were very sensitive to oxygen and the amount of oxygen stored was reproducible by the oxidation at temperatures as low as 373 K. However, Ce3+ species formed in the solid solution of the CeO2-ZrO2(1/1) catalyst were relatively stable. The formation of solid solution facilitated the reducibility of Ce4+ species at low temperature. It was speculated from the titration profile that there were a few steps to oxidize Ce3+ species distributed from surface to bulk in the CeO2-ZrO2(1/1) catalyst." @default.
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- W2087724187 date "2006-02-01" @default.
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- W2087724187 title "Oxidation behavior of reduced (CeO2)1−x-(ZrO2)x (x=0, 0.2, 0.5) catalysts" @default.
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- W2087724187 doi "https://doi.org/10.1016/j.jallcom.2004.12.134" @default.
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