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- W2087738462 abstract "Double-peaked ${mathrm{L}}_{mathrm{III}}$-edge x-ray-absorption (XA) spectra are reported for various compounds of Np. Related high-pressure studies of ${mathrm{UO}}_{3}$ support the idea that these peaks are due to core-ionized final states with different 5f occupancies reflecting the correlated electronic ground state. The weighted mean ${mathrm{L}}_{mathrm{III}}$-XA positions shift to higher energies with decreasing 5f occupancy and, for nonmetallic compounds, depend monotonically on the respective $^{237}mathrm{Np}$ Mossbauer isomer shifts. Deviations from this correlation are observed for metallic compounds due to conduction-electron contributions to the isomer shift." @default.
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- W2087738462 date "1989-12-11" @default.
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- W2087738462 title "Electronic structure of actinide compounds from<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>L</mml:mi></mml:mrow><mml:mrow><mml:mi mathvariant=normal>III</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>-edge x-ray absorption" @default.
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- W2087738462 doi "https://doi.org/10.1103/physrevlett.63.2680" @default.
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