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• W2087781717 abstract "The room temperature structure of Bi0.75Sr0.25MnO3 has been fitted to high-resolution synchrotron X-ray and time-of-flight neutron powder diffraction data. Constrained structural models were refined using a (1200) Pn11 supercell (a=11.0286(2)Å, b=7.7351(1)Å, c=5.53419(9)Å, and α=89.894(1)°) of the underlying Pnma perovskite structure. The best-fit model evidences a 3:1 Mn3+/Mn4+charge ordering with only 30% of the ideal separation of bond valence sums. An ordered intergrowth of antiferro-orbitally ordered (LaMnO3 type) and charge and ferro-orbitally ordered (YBaMn2O6 type) blocks is observed. Off-centre Bi/Sr displacements are ferroelectrically ordered in this model." @default.
• W2087781717 created "2016-06-24" @default.
• W2087781717 creator A5005746288 @default.
• W2087781717 creator A5068640233 @default.
• W2087781717 date "2006-05-01" @default.
• W2087781717 modified "2023-09-27" @default.
• W2087781717 title "Combined powder neutron and X-ray diffraction study of charge and orbital order in Bi0.75Sr0.25MnO3" @default.
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• W2087781717 doi "https://doi.org/10.1016/j.jssc.2006.01.050" @default.
• W2087781717 hasPublicationYear "2006" @default.
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