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- W2087863107 abstract "The nonprotonated member, 1 (n = 6), of the previously established nanosized nu3-octahedral [H(6-n)Pt6Ni38(CO)48]n- series (n = 3-6) has been isolated from an aprotic synthetic route and stabilized as the crystal-ordered cyclohexane/acetonitrile-solvated [NMe4]+ salt. A highly precise X-ray determination (cubic; Pa3; Z = 4 with 1 possessing -3 site symmetry) has allowed a comparative analysis of the nonprotonated pseudo-D3d structure of 1 with the monoprotonated structure of 2 (n = 5), which constitutes the only previously reported complete geometry of any member of this extraordinary Pt6-encapsulated nu3-octahedral Pt6Ni38 cluster series." @default.
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- W2087863107 date "2006-09-27" @default.
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- W2087863107 title "Aprotic Synthesis and Structural Determination of the Nanosized Nonprotonated ν<sub>3</sub>-Octahedral [Pt<sub>6</sub>Ni<sub>38</sub>(CO)<sub>48</sub>]<sup>6</sup><sup>-</sup> Hexaanion Stabilized as a Cubic Solvated [NMe<sub>4</sub>]<sup>+</sup> Salt" @default.
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- W2087863107 doi "https://doi.org/10.1021/ic060648y" @default.
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