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- W2087872005 abstract "An addition reaction of dinuclear [(η6-C6Me6)Ru(η3, 1-exo-syn-CH2CHCHCHO)]2(BF4)2 (1) with different Lewis bases in acetone results in the formation of mononuclear [(η6-C6Me6)Ru(η3-exo-syn-CH2CHCHCHO)(L)](BF4) (L = PMe3, 2; PPh3, 3; PHPh2, 4; Ph2PEtPy, 6; CO, 7) and dinuclear [{(η6-C6Me6)Ru(η3-exo-syn-CH2CHCHCHO)}2(μ2-dppe)](BF4)2 (5). The addition of Ph2PCH2CH2PPh2 to the dinuclear product 1 affords 5 which show a bridging phosphine between two ruthenium centers. A comparative study of the new cationic arene derivatives and the corresponding isoelectronic Cp*Ru(heteropentadienyl) is established. All compounds were characterized by IR spectroscopy, high resolution mass spectrometry, NMR spectroscopy and the crystal structures of 2 and 3 are also described." @default.
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- W2087872005 date "2013-05-15" @default.
- W2087872005 modified "2023-10-17" @default.
- W2087872005 title "Synthesis and Characterization of η<sup>6</sup>-Arene Ruthenium Complexes Bearing Oxopentadienyl and Phosphine Ligands" @default.
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- W2087872005 doi "https://doi.org/10.1002/zaac.201300104" @default.
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