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- W2087912417 abstract "The molecular weight of the silicate ion in aqueous solutions of potassium silicate (SiO2:K2O mole ratio of 3.8:1), both alone and in the presence of various salts and acids, was investigated by means of light-scattering techniques. Angular-dependence data are given for solutions with molecular weight greater than about 105 (results at lower molecular weights did not appear to be meaningful in terms of the main solute). The time dependence of the molecular weight of the silicate ion was determined at one or two concentrations for NH4Cl, (NH4)2SO4, (NH4)2CO3, H3BO3, CH3COOH, H3PO4, NaHCO3, KHCO3, (NH4)2C2O4, isopropyl alcohol, KH2PO4, K2HPO4, NaH2PO4, Na2HPO4, NH4H2PO4, (NH4)2HPO4, Na2SO4, K2SO4, NaC1, KCl, and LiCl. The effects of different temperatures and concentrations were studied for KCl and for acetic acid. The influence of additions of various amounts of alkali or of excess acid, alone or in the presence of salt, on the molecular weight of the silicate ion was also determined. The results of the present investigation are discussed in terms of those of other investigators and in relation to possible models for the method of polymerization." @default.
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- W2087912417 date "1953-04-01" @default.
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- W2087912417 title "The polymerization of aqueous potassium silicate solutions" @default.
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