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- W2087938624 abstract "Abstract Laccase‐catalysed oxidation of ergot alkaloids in the absence of chemical mediators allowed the unexpected isolation of the mono‐hydroxylated derivatives of compounds 2 – 7 . Structure determination by NMR techniques clearly indicated that hydroxylation took place at the C‐4 benzylic position. Quite notably, the proposed protocol allowed, for the first time, functionalisation at the C‐4 position of the ergoline skeleton. Depending on the absence or on the presence of a C‐10 α‐methoxy substituent, hydroxylation was either stereoselective (furnishing C‐4α OH derivatives) or gave rise to a C‐4α/C‐4β OH mixture in a 2:1 ratio, respectively." @default.
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- W2087938624 date "2012-07-09" @default.
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- W2087938624 title "The Quest for New Mild and Selective Modifications of Natural Structures: Laccase-Catalysed Oxidation of Ergot Alkaloids Leads to Unexpected Stereoselective C-4 Hydroxylation" @default.
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- W2087938624 doi "https://doi.org/10.1002/chem.201201076" @default.
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