Matches in SemOpenAlex for { <https://semopenalex.org/work/W2087956668> ?p ?o ?g. }
Showing items 1 to 73 of
73
with 100 items per page.
- W2087956668 endingPage "480" @default.
- W2087956668 startingPage "478" @default.
- W2087956668 abstract "Electron-transfer reactions between the µ-peroxo-cobalt(III) complexes [(H3N)5Co(µ-O2)Co(NH3)5]4+(1), [(H3N)4Co(µ-O2)(µ-NH2)Co(NH3)4]3+(2), and [(L–L)2Co(µ-O2)(µ-NH2)Co(L–L)2]3+[L–L = ethylenediamine (3), 2,2′-bipyridyl (4), or 1,10-phenanthroline (5)] and [Ru(bipy)3]3+(bipy = 2,2′-bipyridyl) have been investigated. The reactants have been generated by the electron-transfer quenching of the excited state of [Ru(bipy)3]2+ by the corresponding µ-superoxo-complexes using flash photolysis. The half-wave potentials measured by polarography for complexes (3), (4), and (5) are 1.00 ± 0.05, 1.04 ± 0.05, and 1.04 ± 0.05 V respectively. The observed rate constants are used to calculate the self-exchange electron-transfer rate constants for the bridged cobalt(III) complexes. The Marcus cross relationship has been used to predict the rate constants determined earlier for the electron-transfer reaction between (3) and the superoxo-forms of complexes (1), (4), and (5)." @default.
- W2087956668 created "2016-06-24" @default.
- W2087956668 creator A5043040907 @default.
- W2087956668 creator A5083110620 @default.
- W2087956668 date "1981-01-01" @default.
- W2087956668 modified "2023-10-16" @default.
- W2087956668 title "Flash-photolysis studies of the electron-transfer reactions of dioxygen complexes of cobalt(III) with tris(2,2′-bipyridyl)ruthenium(III)" @default.
- W2087956668 doi "https://doi.org/10.1039/dt9810000478" @default.
- W2087956668 hasPublicationYear "1981" @default.
- W2087956668 type Work @default.
- W2087956668 sameAs 2087956668 @default.
- W2087956668 citedByCount "4" @default.
- W2087956668 crossrefType "journal-article" @default.
- W2087956668 hasAuthorship W2087956668A5043040907 @default.
- W2087956668 hasAuthorship W2087956668A5083110620 @default.
- W2087956668 hasConcept C121332964 @default.
- W2087956668 hasConcept C121745418 @default.
- W2087956668 hasConcept C123669783 @default.
- W2087956668 hasConcept C13472781 @default.
- W2087956668 hasConcept C148898269 @default.
- W2087956668 hasConcept C161790260 @default.
- W2087956668 hasConcept C178790620 @default.
- W2087956668 hasConcept C179104552 @default.
- W2087956668 hasConcept C181500209 @default.
- W2087956668 hasConcept C185544564 @default.
- W2087956668 hasConcept C185592680 @default.
- W2087956668 hasConcept C2780728571 @default.
- W2087956668 hasConcept C515602321 @default.
- W2087956668 hasConcept C555196967 @default.
- W2087956668 hasConcept C62520636 @default.
- W2087956668 hasConcept C75473681 @default.
- W2087956668 hasConcept C89169741 @default.
- W2087956668 hasConcept C91881484 @default.
- W2087956668 hasConcept C93391505 @default.
- W2087956668 hasConceptScore W2087956668C121332964 @default.
- W2087956668 hasConceptScore W2087956668C121745418 @default.
- W2087956668 hasConceptScore W2087956668C123669783 @default.
- W2087956668 hasConceptScore W2087956668C13472781 @default.
- W2087956668 hasConceptScore W2087956668C148898269 @default.
- W2087956668 hasConceptScore W2087956668C161790260 @default.
- W2087956668 hasConceptScore W2087956668C178790620 @default.
- W2087956668 hasConceptScore W2087956668C179104552 @default.
- W2087956668 hasConceptScore W2087956668C181500209 @default.
- W2087956668 hasConceptScore W2087956668C185544564 @default.
- W2087956668 hasConceptScore W2087956668C185592680 @default.
- W2087956668 hasConceptScore W2087956668C2780728571 @default.
- W2087956668 hasConceptScore W2087956668C515602321 @default.
- W2087956668 hasConceptScore W2087956668C555196967 @default.
- W2087956668 hasConceptScore W2087956668C62520636 @default.
- W2087956668 hasConceptScore W2087956668C75473681 @default.
- W2087956668 hasConceptScore W2087956668C89169741 @default.
- W2087956668 hasConceptScore W2087956668C91881484 @default.
- W2087956668 hasConceptScore W2087956668C93391505 @default.
- W2087956668 hasIssue "2" @default.
- W2087956668 hasLocation W20879566681 @default.
- W2087956668 hasOpenAccess W2087956668 @default.
- W2087956668 hasPrimaryLocation W20879566681 @default.
- W2087956668 hasRelatedWork W2025758883 @default.
- W2087956668 hasRelatedWork W2050653045 @default.
- W2087956668 hasRelatedWork W2055250179 @default.
- W2087956668 hasRelatedWork W2087350074 @default.
- W2087956668 hasRelatedWork W2087956668 @default.
- W2087956668 hasRelatedWork W2094545872 @default.
- W2087956668 hasRelatedWork W2170920176 @default.
- W2087956668 hasRelatedWork W2594193980 @default.
- W2087956668 hasRelatedWork W2951813598 @default.
- W2087956668 hasRelatedWork W3021619178 @default.
- W2087956668 isParatext "false" @default.
- W2087956668 isRetracted "false" @default.
- W2087956668 magId "2087956668" @default.
- W2087956668 workType "article" @default.