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• W2087992013 abstract "Abstract Plutonium monoselenide was studied under high pressure up to 47 GPa, at room temperature, using a diamond anvil cell in an energy dispersive X-ray diffraction facility. At ambient pressure, PuSe has the NaC1-type (B1) structure. The compound has been found to undergo a second-order crystallographic phase transition at around 20 GPa. This phase can be described as a distorted B1 structure, with a rhombohedral symmetry. PuSe transforms to a new phase at around 35 GPa, which can be indexed in the cubic CsCl-type (B2). The volume collapse at this phase transition is 11%. When releasing pressure, we observed a strong hysteresis to the inverse transformation down to 5 GPa. From the pressure-volume relationship, the bulk modulus has been determined to B 0 = 98 GPa and its pressure derivative as B 0 = 2.6. These results are compared to those obtained with other actinide monmictides and monochalcogenides." @default.
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• W2087992013 date "1990-04-01" @default.
• W2087992013 modified "2023-09-25" @default.
• W2087992013 title "High-pressure phases of plutonium monoselenide studied by X-ray diffraction" @default.
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• W2087992013 doi "https://doi.org/10.1080/08957959008203187" @default.
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