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• W2087996064 abstract "NEXAFS measurements have been employed to investigate the Pt-poly-3-methylthiophene (PMeT) interface. The C 1s and S 2p edge characteristics reveal that the polymeric chains are well ordered on the metallic surface even for thicknesses up to 50 A. In its undoped semiconducting state, the polymeric layers lie flat on the Pt with a strong interaction between electron states of the metal and the antibonding Π* band of the PMeT. When PMeT is electrochemically doped to its conducting state, the NEXAFS spectra exhibit changes as a function of thickness. The first layer lies essentially flat on Pt, while the other ones are randomly oriented, according to the intercalation of anions during the oxidation process. The ordering and the homogeneity of the first layers strongly depend on the electric field applied at the Pt-electrolytic medium interface during the electrochemical synthesis." @default.
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• W2087996064 date "1987-12-15" @default.
• W2087996064 modified "2023-09-25" @default.
• W2087996064 title "Chemisorption Geometry of Poly-3-Methylthiophene Electrochemically Deposited on Pt as Observed by NEXAFS" @default.
• W2087996064 cites W1982589349 @default.
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• W2087996064 doi "https://doi.org/10.1209/0295-5075/4/12/009" @default.
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