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- W2088018045 abstract "Persistent aromatic hydrocarbons, including polycyclic aromatic hydrocarbons (PAHs), polychlorinated dibenzo-p-dioxins and furans (PCDD/F), are formed during thermal reactions in combustion systems, such as municipal waste incineration (MWI). Aliphatic products of incomplete combustion (PICs) can react to form simple aromatics that are intermediates or precursors to PAHs and PCDD/F. Products from 600 °C heterogeneous combustion reactions of C2 aliphatics, benzene, and hexachlorobenzene were compared in order to initiate further understanding of the mechanisms of aromatic formation from simple aliphatics. Reaction results (1) suggest that the C2 aliphatics share related thermal decomposition pathways; (2) confirm that Cu plays a critical role in the catalytic action of MWI fly ash; and (3) suggest that Al2O3 plays a unique catalytic role in the formation of aromatic rings from aliphatics. Comparisons of congener distribution patterns of chlorinated benzenes and chlorinated phenols and additional volatile and semivolatile compounds provided the basis for a proposed set of pathways that we believe are important in the formation of aromatics from short-chain aliphatics. CuO and fly ash promote the chlorination of aliphatic intermediates followed by ring formation, whereas Al2O3 selectively catalyzes the formation of nonchlorinated aromatics followed by chlorination." @default.
- W2088018045 created "2016-06-24" @default.
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- W2088018045 date "1997-01-30" @default.
- W2088018045 modified "2023-10-17" @default.
- W2088018045 title "Mechanisms of the Formation of Polychlorinated Benzenes and Phenols by Heterogeneous Reactions of C<sub>2</sub> Aliphatics" @default.
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- W2088018045 doi "https://doi.org/10.1021/es960425e" @default.
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