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• W2088024019 abstract "The spin-orbit excited 2Π32 manifold of 11BAr(X2Π) was observed in a free jet supersonic expansion by laser fluorescence excitation in the B2Σ+ − X2Π (7,0) band. In previous work we observed transitions from the lower 2Π12 manifold. The spin-orbit constant A was determined to equal 10.88±0.08(1σ) cm−, close to a simple estimate, 23ΔE = 10.17 cm−, where ΔE is the boron 2p2P32−2P12 spin-orbit splitting. The near equality of experimental and theoretical values of A suggests that the boron 2p orbital is not strongly affected by the weak, nonbonding BAr interaction." @default.
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• W2088024019 date "1995-02-01" @default.
• W2088024019 modified "2023-09-28" @default.
• W2088024019 title "Spin-orbit splitting in the ground X 2Π electronic state of the BAr van der Waals complex" @default.
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• W2088024019 doi "https://doi.org/10.1016/0009-2614(94)01468-b" @default.
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