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• W2088049412 abstract "Reaction of YbCp2(DME) (Cp  cyclopentadienyl; DME = 1,2-dimethoxyethane) with MCl2 (M  Hg, Cd, Zn, Pb, Sn, Cu, Pd, or Co) or MCl (M  Ag, Cu or Tl) in tetrahydrofuran (THF) gives the metal M and YbCp2Cl(THF)0.5, generally in excellent yield, with small amounts of TlCp and CoCp2 also detected from TlCl and CoCl2 respectively. Similarly, YbCp2X(THF) (X  Br or l) and YbCp2Cl(DME)0.5 have been prepared in good yields by analogous oxidation with suitable mercury(II) halides. However YbCp2(DME) and FeCl3 yield ferrocene. In simpler syntheses. YbCp2X(THF)n (X  Cl, n = 0.5; X  Br or I, n = 1) have been obtained by reactions of YbCp2(DME) with C2Cl6 or (CH2X)2 (X  Br or l) in THF, and (YbCp2X)2 by analogous reactions of unsolvated YbCp2 in petroleum ether. The X-ray crystal structure of YbCp2l(THF) (monoclinic, P21/c, a = 8.147(1), b = 13.788(2), c = 14.149(3) Å, β = 105.56(1)°, Z = 4, R = 0.042, for 2324 observed data) shows the complex to be monomeric with formal eight coordination for ytterbium, and with a pseudo-tetrahedral array of the centroids of the Cp rings, oxygen, and iodine (< YbC > 2.565 Å, YbO 2.311(5) Å, Yb = 12.9316(7) Å)." @default.
• W2088049412 created "2016-06-24" @default.
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• W2088049412 date "1996-11-01" @default.
• W2088049412 modified "2023-09-28" @default.
• W2088049412 title "Organolanthanoids XX. The synthesis of YbCp2Cl(THF)0.5 (Cp  cyclopentadienyl; THF  tetrahydrofuran), YbCp2X(THF) (X  Br or I), and (YbCp2X)2 (X  Cl, Br, or I) by oxidation of YbCp2 with metal and organic halides, and the determination of the X-ray crystal structure of YbCp2I(THF)" @default.
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• W2088049412 doi "https://doi.org/10.1016/s0022-328x(96)06473-x" @default.
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