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- W2088067609 abstract "A highly efficient total synthesis of 7-deoxypancratistatin is described. The synthesis features the ready preparation of the phenanthridone skeleton by a Stille-IMDAF cycloaddition cascade. The resulting cycloadduct is converted into a key aldehydic intermediate, which is then induced to undergo a stereospecific decarbonylation reaction using Wilkinson’s catalyst to set the trans B–C ring junction of the target molecule." @default.
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- W2088067609 date "2006-06-01" @default.
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- W2088067609 title "Application of a stereospecific RhCl(PPh3)3 decarbonylation reaction for the total synthesis of 7-(±)-deoxypancratistatin" @default.
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- W2088067609 doi "https://doi.org/10.1016/j.tetlet.2006.03.163" @default.
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