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• W2088075607 abstract "The influence of Cl− and Fe3+ ions on the morphology of pits grown in aluminium thin films was investigated. Under open circuit conditions various morphologies ranging from percolation-cluster-like patterns to dense holes with smooth perimeters were observed. Temporal fluctuations in the free corrosion potential did not reflect significant differences in pit shapes. The growth of two-dimensional pits is likely to be influenced by two main factors: (a) local fluctuation in the electrolyte aggressiveness due to copious hydrogen bubbling at dissolution sites; (b) global restriction of pit growth imposed by the cathodic reactions occurring on the oxidised surface. A spreading percolation model with feed-back is able to reproduce all the morphologies observed and provides a possible explanation to the 1/f2 character of the potential noise." @default.
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• W2088075607 date "1995-08-01" @default.
• W2088075607 modified "2023-10-18" @default.
• W2088075607 title "Two-dimensional pitting corrosion of aluminium thin layers" @default.
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• W2088075607 doi "https://doi.org/10.1016/0378-4371(95)00048-c" @default.
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