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- W2088110928 abstract "The kinetics of the complex formation between S-carboxymethyl-L-cysteine and palladium(II) was studied by using stopped-flow technique in the acidity range from pH 1 to 4 at 25°C. The reaction rate of the formation of 1:1 chelate species is strongly affected by the acidity. The reaction mechanism consisting of five parallel paths which involve Pd2+ and PdOH+, as well as LH−, LH2 and LH3+ ligand species was proposed. Fairly good agreement between the computed and experimentally determined rate constants was found. The equilibrium constants of the complex formation were determined." @default.
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- W2088110928 date "1998-01-01" @default.
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- W2088110928 title "Kinetics of chelate formation between PdII and S-carboxymethyl-L-cystein" @default.
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- W2088110928 doi "https://doi.org/10.1016/s0277-5387(97)00388-4" @default.
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