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• W2088130023 startingPage "3296" @default.
• W2088130023 abstract "The reaction of [H(OEt2)2][B(C6F5)4] with Zn[N(SiMe3)2]2, MgBu2, and {Mg[N(SiMe3)2]2}2 in diethyl ether proceeds in very high yields to give the salts [(Et2O)3ZnN(SiMe3)2][B(C6F5)4] (2), [(Et2O)3MgnBu][B(C6F5)4] (3), and [(Et2O)3MgN(SiMe3)2][B(C6F5)4] (4), respectively. The structures of 2 and 4 were determined by X-ray crystallography; the compounds contain distorted-tetrahedral metal centers and are isostructural. [(Et2O)3ZnCH2CH3][B(C6F5)4] (1) as well as 2−4 catalyze the ring-opening polymerization of epoxides and ε-caprolactone. Cyclohexene oxide is polymerized extremely rapidly to high molecular weight materials, while the polymerization of propene oxide gives low molecular weight materials via a cationic mechanism. The zinc species are more stable than their magnesium analogues and show higher productivities. ε-Caprolactone is polymerized efficiently to high molecular weight polymers." @default.
• W2088130023 created "2016-06-24" @default.
• W2088130023 creator A5039536225 @default.
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• W2088130023 date "2004-05-28" @default.
• W2088130023 modified "2023-10-17" @default.
• W2088130023 title "Novel Zinc and Magnesium Alkyl and Amido Cations for Ring-Opening Polymerization Reactions" @default.
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• W2088130023 doi "https://doi.org/10.1021/om0497691" @default.
• W2088130023 hasPublicationYear "2004" @default.
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