Matches in SemOpenAlex for { <https://semopenalex.org/work/W2088183203> ?p ?o ?g. }
Showing items 1 to 99 of
99
with 100 items per page.
- W2088183203 endingPage "1207" @default.
- W2088183203 startingPage "1197" @default.
- W2088183203 abstract "The rates of the photochemical and thermal decarboxylation of aliphatic acids by lead (IV) tetraacete have been examined by a competition method. Photochemically, pivalic (tertiary) acid decarboxylates at 30° approximately 100 times, and isobutyric (secondary) acid 20 times, faster than n-butyric (primary) acid. The competitive decarboxylations of acids by lead(IV) carried out thermally at 80–100° show a smaller spread in reactivity. The thermal procedure is complicated by further oxidation of the olefinic products by PbIV. Rates of decarboxylation are related to the multibond cleavage of the Pb-carboxylate linkages directly into alkyl radicals and carbon dioxide. The mechanism of the reduction of PbIV is compared to the homolytic decarboxylations of the analogous CoIII, MnIII and CeIV carboxylates." @default.
- W2088183203 created "2016-06-24" @default.
- W2088183203 creator A5010553262 @default.
- W2088183203 creator A5030343286 @default.
- W2088183203 creator A5038130495 @default.
- W2088183203 date "1969-01-01" @default.
- W2088183203 modified "2023-10-09" @default.
- W2088183203 title "Rates of photochemical and thermal decarboxylation of acids by lead (IV) tetraacetate" @default.
- W2088183203 cites W1963688013 @default.
- W2088183203 cites W1965274516 @default.
- W2088183203 cites W1965728514 @default.
- W2088183203 cites W1980417542 @default.
- W2088183203 cites W1995400824 @default.
- W2088183203 cites W1998620092 @default.
- W2088183203 cites W2013336257 @default.
- W2088183203 cites W2016881761 @default.
- W2088183203 cites W2028675195 @default.
- W2088183203 cites W2033823693 @default.
- W2088183203 cites W2034100971 @default.
- W2088183203 cites W2037925286 @default.
- W2088183203 cites W2047663417 @default.
- W2088183203 cites W2053696582 @default.
- W2088183203 cites W2061669123 @default.
- W2088183203 cites W2085705518 @default.
- W2088183203 cites W2129374189 @default.
- W2088183203 cites W2314271346 @default.
- W2088183203 cites W2315796696 @default.
- W2088183203 cites W2318720293 @default.
- W2088183203 cites W2323384396 @default.
- W2088183203 cites W2331366796 @default.
- W2088183203 cites W2332107281 @default.
- W2088183203 cites W2332652629 @default.
- W2088183203 cites W4232503176 @default.
- W2088183203 doi "https://doi.org/10.1016/s0040-4020(01)82693-4" @default.
- W2088183203 hasPublicationYear "1969" @default.
- W2088183203 type Work @default.
- W2088183203 sameAs 2088183203 @default.
- W2088183203 citedByCount "21" @default.
- W2088183203 countsByYear W20881832032015 @default.
- W2088183203 countsByYear W20881832032016 @default.
- W2088183203 countsByYear W20881832032017 @default.
- W2088183203 countsByYear W20881832032020 @default.
- W2088183203 countsByYear W20881832032021 @default.
- W2088183203 countsByYear W20881832032022 @default.
- W2088183203 crossrefType "journal-article" @default.
- W2088183203 hasAuthorship W2088183203A5010553262 @default.
- W2088183203 hasAuthorship W2088183203A5030343286 @default.
- W2088183203 hasAuthorship W2088183203A5038130495 @default.
- W2088183203 hasConcept C139066938 @default.
- W2088183203 hasConcept C155647269 @default.
- W2088183203 hasConcept C161790260 @default.
- W2088183203 hasConcept C175689099 @default.
- W2088183203 hasConcept C178790620 @default.
- W2088183203 hasConcept C185592680 @default.
- W2088183203 hasConcept C2778074193 @default.
- W2088183203 hasConcept C2779186712 @default.
- W2088183203 hasConcept C2779634684 @default.
- W2088183203 hasConcept C2779843069 @default.
- W2088183203 hasConcept C2780178953 @default.
- W2088183203 hasConcept C2780263894 @default.
- W2088183203 hasConcept C2780584575 @default.
- W2088183203 hasConcept C2780595602 @default.
- W2088183203 hasConcept C75473681 @default.
- W2088183203 hasConceptScore W2088183203C139066938 @default.
- W2088183203 hasConceptScore W2088183203C155647269 @default.
- W2088183203 hasConceptScore W2088183203C161790260 @default.
- W2088183203 hasConceptScore W2088183203C175689099 @default.
- W2088183203 hasConceptScore W2088183203C178790620 @default.
- W2088183203 hasConceptScore W2088183203C185592680 @default.
- W2088183203 hasConceptScore W2088183203C2778074193 @default.
- W2088183203 hasConceptScore W2088183203C2779186712 @default.
- W2088183203 hasConceptScore W2088183203C2779634684 @default.
- W2088183203 hasConceptScore W2088183203C2779843069 @default.
- W2088183203 hasConceptScore W2088183203C2780178953 @default.
- W2088183203 hasConceptScore W2088183203C2780263894 @default.
- W2088183203 hasConceptScore W2088183203C2780584575 @default.
- W2088183203 hasConceptScore W2088183203C2780595602 @default.
- W2088183203 hasConceptScore W2088183203C75473681 @default.
- W2088183203 hasIssue "6" @default.
- W2088183203 hasLocation W20881832031 @default.
- W2088183203 hasOpenAccess W2088183203 @default.
- W2088183203 hasPrimaryLocation W20881832031 @default.
- W2088183203 hasRelatedWork W1980256591 @default.
- W2088183203 hasRelatedWork W1983230473 @default.
- W2088183203 hasRelatedWork W2007935352 @default.
- W2088183203 hasRelatedWork W2036388224 @default.
- W2088183203 hasRelatedWork W2064107943 @default.
- W2088183203 hasRelatedWork W2077693726 @default.
- W2088183203 hasRelatedWork W2093927038 @default.
- W2088183203 hasRelatedWork W2395495232 @default.
- W2088183203 hasRelatedWork W3032068284 @default.
- W2088183203 hasRelatedWork W4386305916 @default.
- W2088183203 hasVolume "25" @default.
- W2088183203 isParatext "false" @default.
- W2088183203 isRetracted "false" @default.
- W2088183203 magId "2088183203" @default.
- W2088183203 workType "article" @default.