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- W2088183701 abstract "In anhydrous hydrogen fluoride (aHF) (heterogeneous reaction) B(C6F5)3 transfers all the three aryl groups to XeF2 forming [C6F5Xe]+ salts. Upon addition of KF, the [C6F5Xe] [HF2] salt was isolated in 78.7% yield. [C6F5Xe] [HF2] dissolved in MeCN exhibits significant cation–anion interactions and decomposes within 14 days at 20 °C. The acidity of the aHF solvent determines the nature of the products in the reaction of XeF2 with B(C6F5)3. The reaction path of this new methodical approach of fluorine-aryl substitution in aHF is discussed." @default.
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- W2088183701 date "2001-12-01" @default.
- W2088183701 modified "2023-09-25" @default.
- W2088183701 title "The fluorine-pentafluorophenyl substitution reaction in anhydrous hydrogen fluoride (aHF): a new interesting methodical approach to synthesize pentafluorophenylxenonium salts" @default.
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- W2088183701 doi "https://doi.org/10.1016/s0022-1139(01)00526-7" @default.
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