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- W2088259920 abstract "The hydrolysis equilibria of boric acid in light- and heavy-water solutions containing 3 mol dm−3 of LiClO4 as an ionic medium were studied at 25°C by measuring the lyonium ion concentration with a glass electrode. Analysis of the e.m.f. data indicated the formation of analogous complexes in H2O and D2O: B(OL)4−, B4(OL)142−, and either B2(OL)7− or B3(OL)112− as a minor species. The formation constants ∗βp,q are smaller in D2O than in H2O. These results are consistent with those previously reported for the hydrolysis of cations. It seems that the formation constants Kp,q for the heavy-water system have slightly larger values than those for the light-water system, although this solvent deuterium isotope effect for polyborate complexes is much smaller than that observed for some metal ion hydrolysis species." @default.
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- W2088259920 date "1978-01-01" @default.
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- W2088259920 title "Solvent deuterium isotope effect on hydrolysis of boric acid" @default.
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- W2088259920 doi "https://doi.org/10.1016/0022-1902(78)80433-3" @default.
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