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- W2088290419 abstract "The complex polysaccharide of the leaves of Pereskia aculeata is highly branched, containing units of arabinofuranose, arabinopyranose, galactopyranose, galactopyranosyluronic acid, and rhamnopyranose. Glucopyranose units are also present. The location of 25 molar % of acetate ester groups was determined using modified Bouveng procedures, one of the changes being the use of refluxing methanolic sodium methoxide for the removal of N-methyl-N-phenylcarbamoyl groups. With the aid of g.l.c.-m.s. on a capillary column of DB-210, which separated the various isomeric mono-, di-, and tri-O-methyl arabinitol acetates, and by examination of e.i. fragmentation patterns of various derivatives deuterated at C-1, the O-acetyl groups were located. They were found mainly as monosubstituents at O-2 and O-3 of nonreducing arabinofuranosyl end-groups and at O-2 of 4-O-substituted galacto- and gluco-pyranosyl units." @default.
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- W2088290419 date "1990-07-01" @default.
- W2088290419 modified "2023-10-18" @default.
- W2088290419 title "Location of O-acetyl groups in the heteropolysaccharide of the cactus Pereskia aculeata" @default.
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- W2088290419 doi "https://doi.org/10.1016/0008-6215(90)84243-n" @default.
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