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• W2088329735 endingPage "4816" @default.
• W2088329735 startingPage "4810" @default.
• W2088329735 abstract "Reaction of the (alkyl)(alkenyl)(alkynyl)iridium(III) complex [Ir(CH3)(CHCHNEt3)(C⋮C(p-C6H4CH3))(CO)(PPh3)2]ClO4 (3) with aqueous HCl initiates an intramolecular coupling reaction between −CH3 and −C⋮C(p-C6H4CH3) groups to give [Ir(C(CH3)CH(p-C6H4CH3)(CHCHNEt3)(Cl)(CO)(PPh3)2]ClO4 (5), which further reacts with aqueous HCl to produce [Ir(CHCHNEt3)(Cl)2(CO)(PPh3)2]ClO4 (6) and cis-CH3CHCH(p-C6H4CH3) (7). Complex 5 yields the C−C coupling product [(p-C6H4CH3)HCC(CH3)CHCHNEt3]ClO4 (8) when it is refluxed in CHCl3. The (alkyl)bis(alkynyl)iridium(III) compound Ir(CH3)(C⋮C(p-C6H4CH3))2(CO)(PPh3)2 (4) reacts with aqueous HCl to give H2CCCH(p-C6H4CH3) (9). Complex 3 reacts with excess DCl to give the d5 isotopomer CD3CDCD(p-C6H4CH3) (7-d5), while the reaction of 4 with DCl gives the d1 isotopomer H2CCCD(p-C6H4CH3) (9-d1). Plausible reaction pathways are discussed for the formation of 7 and 9 and for the H/D exchange to give the isotopomer 7-d5." @default.
• W2088329735 created "2016-06-24" @default.
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• W2088329735 date "1999-10-21" @default.
• W2088329735 modified "2023-09-23" @default.
• W2088329735 title "Reaction of an (Alkyl)(alkenyl)(alkynyl)iridium(III) Complex with HCl: Intramolecular C−C Bond Formation from Alkyl, Alkenyl, and Alkynyl Groups Coordinated to “Ir(CO)(PPh₃)₂”. H/D Exchange between CH₃ and DCl" @default.
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• W2088329735 doi "https://doi.org/10.1021/om9903442" @default.
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