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• W2088351630 endingPage "17876" @default.
• W2088351630 startingPage "17867" @default.
• W2088351630 abstract "U-shaped donor-bridge-acceptor molecules with different electronic couplings have been investigated as a function of temperature in solvents with slow polarization relaxation, in particular, N-methylacetamide (NMA) and N-methylpropionamide (NMP). At high temperature, the electron-transfer rate is well described by a nonadiabatic model; however, the rate at low temperature is controlled by the solvent friction. The change of the electron-transfer mechanism is discussed and compared with theoretical models." @default.
• W2088351630 created "2016-06-24" @default.
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• W2088351630 date "2005-11-25" @default.
• W2088351630 modified "2023-10-16" @default.
• W2088351630 title "Solvent Friction Effect on Intramolecular Electron Transfer" @default.
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• W2088351630 doi "https://doi.org/10.1021/ja055596a" @default.
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• W2088351630 hasPublicationYear "2005" @default.
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