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- W2088360038 abstract "Abstract Our published work on stress evolution in CoFe films [Electrochim. Acta 55 (2010) 9035], indicated that adsorption/desorption of hydrogen is a primary cause of tensile stress which increases with the increase of Fe-content in deposit and decrease of current efficiency, i.e. higher supply of protons to the electrode surface. Using the electroanalytical techniques in this study it has been demonstrated that a higher supply of protons to the electrode surface with increase of Fe 2+ concentrations in solution brings about higher Fe-content in deposit and lower current efficiency. First, it was found that the reduction rate of H + from the solution is faster on CoFe surface with higher Fe-content in CoFe deposit. Second, it was found that higher concentrations of Fe 2+ in solution bring about higher surface concentration of H + through the Fe 2+ hydrolysis reaction, i.e. Fe 2+ + HOH = FeOH + + H + . The proton liberated through hydrolysis reaction is reduced as soon as it is formed, together with other electroactive species." @default.
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- W2088360038 date "2011-12-01" @default.
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- W2088360038 title "Relationship of Fe2+ concentration in solution and current efficiency in electrodeposition of CoFe films" @default.
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- W2088360038 doi "https://doi.org/10.1016/j.electacta.2011.08.066" @default.
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