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• W2088381544 startingPage "9264" @default.
• W2088381544 abstract "Triangular ortho-phenylene ethynylene (o-PE) cyclic trimers represent a novel member of shape-persistent macrocycles. Shape-persistent cyclic structures remain of great interest as molecular components in the fields of supramolecular materials, host−guest chemistry, and materials science. Novel discotic liquid crystalline properties are reported from triangular-shaped o-PE macrocycles containing branched alkoxy- and/or triethylene glycol (TEG) side chains using polarized optical microscopy (POM), differential scanning calorimetry (DSC), and X-ray diffraction (XRD). The macrocycles self-assemble into thermotropic rectangular columnar (Colr) (for M1), hexagonal columnar (Colh) (for M2), and discotic nematic (for M3) mesophases at room temperature. This work shows clearly that electron-rich PE macrocycles can form LC materials. Alkyl side chains in M1 promote order, while hydrophilic side chains of M2 generate an amphiphilic structure that provides a different driving force for organization. The ability to create ordered self-assembling materials from these novel electron-rich macrocycles is important in nanotechnology." @default.
• W2088381544 created "2016-06-24" @default.
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• W2088381544 date "2006-06-30" @default.
• W2088381544 modified "2023-10-16" @default.
• W2088381544 title "Liquid Crystalline Order from <i>ortho</i>-Phenylene Ethynylene Macrocycles" @default.
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• W2088381544 doi "https://doi.org/10.1021/ja060354b" @default.
• W2088381544 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16848425" @default.
• W2088381544 hasPublicationYear "2006" @default.
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