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• W2088386321 abstract "In order to investigate the influence of the chromium content on the oxidation performance of the chromium-alloyed Mo5Si3, five kinds of sputter-deposited nanocrystalline (MoxCr1−x)5Si3 (x = 1, 0.78, 0.75, 0.64, 0.57) films have been prepared on Ti−6A1−4 V alloy substrates by double-cathode glow discharge. X-ray diffraction, scanning electron microscopy, and transmission electron microscopy have been used to characterize the nanocrystalline (MoxCr1−x)5Si3 (x = 1, 0.78, 0.75, 0.64, 0.57) films. The as-deposited films were free of crack having metallurgical bonding with a substrate and consisted of an outer (MoxCr1−x)5Si3 layer and an inner diffusion layer. The inner diffusion layer could be divided into a β-phase layer with high Mo content (>10 wt %) and an α′′/α′ layer with low Mo content (<10 wt %). During the cyclic oxidation test at 800 °C in air, for the monolithic nanocrystalline Mo5Si3 film, local spallation of the oxide scale took place by internal stresses after 5 min of oxidation, and severe spallation of the oxide scale sharpened the mass loss with an increase in the oxidation time. However, in the case of nanocrystalline chromium-alloyed Mo5Si3 films, spallation resistance to thermal cycling increased significantly with an increase in the chromium addition, and particularly for the (Mo0.57Cr0.43)5Si3 film, no sign of spallation or microcracking occurred even after 240 h at 800 °C because of the formation of a fine-grain protective scale." @default.
• W2088386321 created "2016-06-24" @default.
• W2088386321 creator A5014816129 @default.
• W2088386321 creator A5052885144 @default.
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• W2088386321 date "2009-12-31" @default.
• W2088386321 modified "2023-09-25" @default.
• W2088386321 title "Influence of Chromium Alloying on the Cyclic Oxidation Behavior of Nanocrystalline (Mo_<i>x</i>Cr_1−<i>x</i>)₅Si₃ Films at 800 °C in Air" @default.
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• W2088386321 doi "https://doi.org/10.1021/am900794f" @default.
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