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- W2088390004 startingPage "1669" @default.
- W2088390004 abstract "By CNDO calculations considering the 3d orbitals of the chlorine atom, the infrared absorption intensity of the C–H stretching vibration band in chloroform vapor has been discussed in comparison with those of methyl chloride and methylene chloride. The absolute intensities of the fundamental and the first-overtone bands of these compounds have been calculated in view of the mechanical and the electrical anharmoniciteis of the vibrating bond. From the results of these calculations, it was revealed that the contribution of the electrical properties of the vibrating bond to the abnormal absorption intensity of the C–H stretching vibration band in chloroform vapor is really greater than that of the mechanical anharmonicity." @default.
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- W2088390004 date "1972-06-01" @default.
- W2088390004 modified "2023-09-25" @default.
- W2088390004 title "The Abnormal Absorption Intensity of the C–H Stretching Vibration Band in Chloroform Vapor. II." @default.
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- W2088390004 doi "https://doi.org/10.1246/bcsj.45.1669" @default.
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