FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2088394580> ?p ?o ?g. }

• W2088394580 endingPage "732" @default.
• W2088394580 startingPage "728" @default.
• W2088394580 abstract "Although terminal chalcogeno ligands are well known for the group 5 and 6 transition metals, they are highly unusual for the oxophilic group 4 metals and unknown so far for the lanthanides or actinides. Cs3UP2S8, is the first actinide compound containing a terminal M=S group. It was synthesized by reacting uranium metal, Cs2S, S, and P2S5 in a 4:1:8:3 ratio at 700 °C in an eutectic LiCl/CsCl mixture. The crystal structure was determined by single-crystal X-ray diffraction techniques. Cs3UP2S8 crystallizes in the rhombohedral space group R [a = 15.5217(8) Å; c = 35.132(2) Å, V = 8305.0(8) Å3, Z = 18]. The crystal structure is based on a tetrahedral network type, wherein the uranium atoms are coordinated by a unusual sulfido moiety and thiophosphate groups in a pseudo-tetrahedral fashion. The U=S distance of 2.635(3) Å observed in the sulfide moiety is approx. 0.2 Å shorter than the average U–S single bond length, indicating a double-bond type character." @default.
• W2088394580 created "2016-06-24" @default.
• W2088394580 creator A5033441578 @default.
• W2088394580 creator A5040110713 @default.
• W2088394580 creator A5079990250 @default.
• W2088394580 date "2013-03-14" @default.
• W2088394580 modified "2023-10-03" @default.
• W2088394580 title "Cs₃UP₂S₈, a Coordination Polymer Containing the Unprecedented [U=S]²⁺Sulfidouranium(2+) Moiety" @default.
• W2088394580 cites W113635665 @default.
• W2088394580 cites W1480131656 @default.
• W2088394580 cites W1500320956 @default.
• W2088394580 cites W1514296067 @default.
• W2088394580 cites W1967049886 @default.
• W2088394580 cites W1967298304 @default.
• W2088394580 cites W1968506363 @default.
• W2088394580 cites W1970924788 @default.
• W2088394580 cites W1984213428 @default.
• W2088394580 cites W1995760792 @default.
• W2088394580 cites W1995768500 @default.
• W2088394580 cites W2001348887 @default.
• W2088394580 cites W2006105265 @default.
• W2088394580 cites W2007751590 @default.
• W2088394580 cites W2022685597 @default.
• W2088394580 cites W2022941219 @default.
• W2088394580 cites W2026838218 @default.
• W2088394580 cites W2032301535 @default.
• W2088394580 cites W2039161072 @default.
• W2088394580 cites W2045057278 @default.
• W2088394580 cites W2045298373 @default.
• W2088394580 cites W2060014402 @default.
• W2088394580 cites W2061036387 @default.
• W2088394580 cites W2061757915 @default.
• W2088394580 cites W2062142701 @default.
• W2088394580 cites W2063646546 @default.
• W2088394580 cites W2077123858 @default.
• W2088394580 cites W2079875934 @default.
• W2088394580 cites W2080831568 @default.
• W2088394580 cites W2087288326 @default.
• W2088394580 cites W2092506923 @default.
• W2088394580 cites W2102788841 @default.
• W2088394580 cites W2104286063 @default.
• W2088394580 cites W2104561051 @default.
• W2088394580 cites W2106665350 @default.
• W2088394580 cites W2117157661 @default.
• W2088394580 cites W2124240587 @default.
• W2088394580 cites W2124944562 @default.
• W2088394580 cites W2131350133 @default.
• W2088394580 cites W2134624318 @default.
• W2088394580 cites W2152855754 @default.
• W2088394580 cites W2163898547 @default.
• W2088394580 cites W2167590372 @default.
• W2088394580 cites W2206945395 @default.
• W2088394580 cites W2949190170 @default.
• W2088394580 cites W2950146696 @default.
• W2088394580 cites W2950774806 @default.
• W2088394580 cites W2951080081 @default.
• W2088394580 cites W2951844106 @default.
• W2088394580 cites W2952536584 @default.
• W2088394580 cites W4254061644 @default.
• W2088394580 doi "https://doi.org/10.1002/zaac.201200562" @default.
• W2088394580 hasPublicationYear "2013" @default.
• W2088394580 type Work @default.
• W2088394580 sameAs 2088394580 @default.
• W2088394580 citedByCount "4" @default.
• W2088394580 countsByYear W20883945802013 @default.
• W2088394580 countsByYear W20883945802016 @default.
• W2088394580 crossrefType "journal-article" @default.
• W2088394580 hasAuthorship W2088394580A5033441578 @default.
• W2088394580 hasAuthorship W2088394580A5040110713 @default.
• W2088394580 hasAuthorship W2088394580A5079990250 @default.
• W2088394580 hasConcept C115624301 @default.
• W2088394580 hasConcept C135788738 @default.
• W2088394580 hasConcept C145148216 @default.
• W2088394580 hasConcept C155860418 @default.
• W2088394580 hasConcept C178790620 @default.
• W2088394580 hasConcept C179104552 @default.
• W2088394580 hasConcept C185592680 @default.
• W2088394580 hasConcept C191897082 @default.
• W2088394580 hasConcept C192562407 @default.
• W2088394580 hasConcept C201770740 @default.
• W2088394580 hasConcept C2776568683 @default.
• W2088394580 hasConcept C2778278100 @default.
• W2088394580 hasConcept C2781311116 @default.
• W2088394580 hasConcept C544153396 @default.
• W2088394580 hasConcept C555451288 @default.
• W2088394580 hasConcept C71240020 @default.
• W2088394580 hasConcept C8010536 @default.
• W2088394580 hasConceptScore W2088394580C115624301 @default.
• W2088394580 hasConceptScore W2088394580C135788738 @default.
• W2088394580 hasConceptScore W2088394580C145148216 @default.
• W2088394580 hasConceptScore W2088394580C155860418 @default.
• W2088394580 hasConceptScore W2088394580C178790620 @default.
• W2088394580 hasConceptScore W2088394580C179104552 @default.
• W2088394580 hasConceptScore W2088394580C185592680 @default.
• W2088394580 hasConceptScore W2088394580C191897082 @default.
• W2088394580 hasConceptScore W2088394580C192562407 @default.
• W2088394580 hasConceptScore W2088394580C201770740 @default.
• W2088394580 hasConceptScore W2088394580C2776568683 @default.

• next