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- W2088396463 abstract "Flash vacuum pyrolysis of triphenyl- and trimethylboroxin and subsequent trapping of the gas phase products in a large excess of argon at T < 20 K allows matrix isolation and characterization by IR spectroscopy of phenyl(oxo)borane and methyl(oxo)borane. The nature of the matrix isolated species, monomeric CH3BO, 1:1 dimer complex of CH3BO, (CH3BO)2, and (CH3BO)3, depends strongly on the trapping temperature and matrix host gas (Ar vs Xe) with the boroxin dominating at 30 K (Ar) or 55 K (Xe). An ab initio investigation (second-order Møller−Plesset perturbation theory) of the potential energy surface for trimerization of CH3BO is in agreement with the experimental observations." @default.
- W2088396463 created "2016-06-24" @default.
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- W2088396463 date "2007-11-08" @default.
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- W2088396463 title "Reversible Formation of Organyl(oxo)boranes (RBO) (R = C<sub>6</sub>H<sub>5</sub> or CH<sub>3</sub>) from Boroxins ((RBO)<sub>3</sub>): A Matrix Isolation Study" @default.
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- W2088396463 doi "https://doi.org/10.1021/om061057i" @default.
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