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- W2088397466 abstract "Abstract The NHC‐stabilized C–F activation product [Ni( i Pr 2 Im) 2 (F)(C 6 F 5 )] ( 1 ) was isolated from the reaction of [Ni(cod) 2 ] with 1,3‐diisopropylimidazol‐2‐ylidene ( i Pr 2 Im) and hexafluorobenzene. Square‐planar (pentafluorophenyl)nickel complexes of the type [Ni( i Pr 2 Im) 2 (X)(C 6 F 5 )] were obtained by a systematic derivatization of 1 . The reaction of 1 with silylated compounds and organyllithium compounds led smoothly to replacement of the fluorido ligand in 1 by halogenido, trifluoromethanesulfonato, cyanido, organyl, selenolato, thiolato, and hydrido ligands. According to these procedures, the NHC‐stabilized (pentafluorophenyl)nickel complexes [Ni( i Pr 2 Im) 2 (X)(C 6 F 5 )] (X = Cl 2 , I 3 , CF 3 SO 3 4 , CN 5 ), [Ni( i Pr 2 Im) 2 (R)(C 6 F 5 )] (R = Me 6 , Ph 7 , C 2 Ph 8 , η 1 ‐Cp 9 ), [Ni( i Pr 2 Im) 2 (SR)(C 6 F 5 )] (R = Ph 10 , n Pr 11 ), [Ni( i Pr 2 Im) 2 (SeR)(C 6 F 5 )] (R = Ph 12 , i Pr 13 ), and [Ni( i Pr 2 Im) 2 (H)(C 6 F 5 )] ( 14 ) were prepared. The complexes 4 , 6 . 9 , 11 , 13 and 14 were structurally characterized.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)" @default.
- W2088397466 created "2016-06-24" @default.
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- W2088397466 date "2008-05-28" @default.
- W2088397466 modified "2023-09-23" @default.
- W2088397466 title "Square‐Planar (Pentafluorophenyl)nickel(II) Complexes by Derivatization of a C–F Activation Product" @default.
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- W2088397466 doi "https://doi.org/10.1002/ejic.200800213" @default.
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