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- W2088397781 abstract "By the use of various boron compounds methyl methacrylate and styrene were copolymerized under photoirradiations at −20°C. The alternately regulating activities of the boron compounds in the copolymerizations were in the following order: boron trichloride > ethylboron dichloride > boron trifluoride > diethylboron chloride ≫ triethylboron (≃0). Boron trichloride and ethylboron dichloride exhibited such high regulating activities that their presence in 1 mol% in the charged methyl methacrylate was sufficient to complete equimolar alternating copolymerization. The alternating copolymerization proceeded in the steady state. The copolymerization rates decreased in the following order: boron trichloride ≫ ethylboron dichloride > diethylboron chloride ≫ triethylboron (≃0). The cotacticities of methyl methacrylate-centered triads in the resulting copolymers were identical to those prepared with boron trichloride, ethylboron dichloride, and diethylboron chloride. The mechanism of the alternating copolymerization is discussed." @default.
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- W2088397781 date "1981-10-01" @default.
- W2088397781 modified "2023-10-18" @default.
- W2088397781 title "Polymerization of coordinated monomers. XVII. Alternating copolymerization of methyl methacrylate with styrene by boron compounds" @default.
- W2088397781 doi "https://doi.org/10.1002/pol.1981.170191018" @default.
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