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- W2088406687 abstract "An expeditious approach to (±)-aphanorphine has been established using readily available starting materials. The present synthesis relies on the direct assembly between N-methylpyrrolidone (NMP) and 2-bromoanisaldehyde, which takes place through Et3B/air-mediated transformation of the α-nitrogen-substituted sp3C–H bond, and features a new design concept for the synthesis of the tricyclic 3-benzazepine skeleton." @default.
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- W2088406687 date "2008-07-01" @default.
- W2088406687 modified "2023-10-12" @default.
- W2088406687 title "Synthesis of (±)-aphanorphine: a new approach to tricyclic 3-benzazepine scaffold using two radical C–C bond-forming reactions" @default.
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- W2088406687 doi "https://doi.org/10.1016/j.tetlet.2008.05.058" @default.
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