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- W2088409990 abstract "Abstract The behavior of 1,3,5-trialkyl-1,3,5-hexahydrotriazines ( A ) in a variety of solvents was investigated by 1 H NMR. A are stable for linear alkyls in deuterated solvents such as chloroform, benzene, acetone, dioxane, dimethylsulfoxide and acetonitrile. In case of branched alkyls, A are in equilibrium with N -methylenealkylamines ( B ). The A / B ratio depends on solvent, concentration of the sample and temperature. A react easily with methanol and lead to the formation of N -(methoxymethyl)amines ( C ), which are in equilibrium with B . Both the quantitative evaluation of A – B equilibrium in solutions as well as the formation of C in methanol was described for the first time." @default.
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- W2088409990 date "2008-12-01" @default.
- W2088409990 modified "2023-09-23" @default.
- W2088409990 title "1,3,5-Trialkyl-hexahydro-1,3,5-triazines–N-methylenealkylamines equilibria. 1H NMR studies in solutions" @default.
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- W2088409990 doi "https://doi.org/10.1016/j.molstruc.2008.05.019" @default.
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