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- W2088472901 abstract "The interaction of cobalt(II) tetraphenylporphyrin (CoTPP) and cobalt(II) tetrakis-(3,5-di-tert-butylphenyl)porphyrin (CoTTBPP) with a Ag(111) surface has been investigated with photoelectron spectroscopy (XPS/UPS). It is demonstrated that these adsorbed metal complexes are excellent model systems for studying the electronic interaction between a coordinated metal ion and a metal surface. The photoelectron spectra and work function data provide evidence that the electronic interaction between the cobalt ion and the silver surface results in a transfer of electron density from the surface to the ion. The presence of an additional electronic state located ∼1 eV above the singly occupied molecular orbital (SOMO) of the metalloporphyrins is consistent with a molecular orbital (MO) model of the Co−Ag interaction as is the fact that the energetic position of this state depends on the distance between the Co ion and the Ag surface. The adsorbate-induced work function changes for the saturated monolayers amount to −0.72 eV for CoTPP and −0.91 eV for CoTTBPP. For comparison, we also present data of monolayer films of tetraphenylporphyrin and zinc(II) tetraphenylporphyrin." @default.
- W2088472901 created "2016-06-24" @default.
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- W2088472901 date "2007-02-01" @default.
- W2088472901 modified "2023-10-18" @default.
- W2088472901 title "Interaction of Cobalt(II) Tetraarylporphyrins with a Ag(111) Surface Studied with Photoelectron Spectroscopy" @default.
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- W2088472901 doi "https://doi.org/10.1021/jp0652345" @default.
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