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- W2088486526 abstract "Abstract Large-cage occupancy of hydrogen (H 2 ) in the H 2 +tetrahydrofuran (THF) hydrates has been ever reported only in the ex situ spectroscopic measurements with the quenched hydrate sample. In the present study, to verify the proof-of-concept for the large-cage occupancy of H 2 competitive with THF, in situ Raman spectra of H 2 in the H 2 +THF mixed hydrates were detected at 74.3 MPa and 265 K without the quenching procedure. The Raman spectra reveal that H 2 molecules occupy a part of large cages of the H 2 +THF mixed hydrates at a thermodynamically unstable region of simple H 2 hydrate." @default.
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- W2088486526 date "2013-09-01" @default.
- W2088486526 modified "2023-09-23" @default.
- W2088486526 title "In situ Raman spectra of hydrogen in large cages of hydrogen+tetrahydrofuran mixed hydrates" @default.
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- W2088486526 doi "https://doi.org/10.1016/j.ces.2013.05.044" @default.
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