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• W2088488384 abstract "The hydroxylation of cyclohexane by t-butyl hydroperoxide using [Fe2O(TPA)2(H2O)2]4+ (1, TPA = tris(2-pyridylmethyl)amine) as the catalyst has been investigated with the use of a syringe pump to control the concentration of the alkyl hydroperoxide. Unlike an alkoxy radical-based radical chain autoxidation mechanism, the reaction observed produces only alcohol (no ketone) with a deuterium kinetic isotope effect of 10, similar to heme-catalyzed hydroxylations. An alkylperoxoiron(III) intermediate can be trapped at −40°C and characterized by a number of spectroscopic methods. A mechanistic scheme is proposed involving this intermediate which either serves as the precursor to the metal-based oxidant or oxidizes the substrate directly." @default.
• W2088488384 created "2016-06-24" @default.
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• W2088488384 date "1997-03-01" @default.
• W2088488384 modified "2023-09-23" @default.
• W2088488384 title "Fe(TPA)-catalyzed alkane hydroxylation can be a metal-based oxidation" @default.
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• W2088488384 doi "https://doi.org/10.1016/s1381-1169(96)00364-0" @default.
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