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- W2088502009 abstract "Abstract Dihapto-coordination of aromatic ligands by electron-rich transition metals can effectively dearomatize the bound aromatic molecule. The pentaammineosmium(II) system forms thermally stable η 2 -complexes with a variety of arenes and aromatic heterocycles, and has been used for a variety of organic transformations on the bound aromatic fragments. The systematic variation of isoelectronic rhenium(I) systems has provided the necessary electronic and steric characteristics needed for a less expensive, chiral alternative to the {Os(NH 3 ) 5 } 2+ system. The {TpRe(CO)(PMe 3 )} system has been shown to form stable dihapto complexes with furan, thiophene and naphthalene. Accordingly, the {TpRe(CO)(PMe 3 )} fragment and analogous {TpRe(CO)(L)} fragments represent the first class of asymmetric surrogates to the pentaammineosmium(II) system." @default.
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- W2088502009 date "2000-12-19" @default.
- W2088502009 modified "2023-09-27" @default.
- W2088502009 title "ChemInform Abstract: Dihapto Binding of Aromatic Molecules by π-Basic Transition Metal Complexes: Development of Alternatives to the {Os(NH3)5}2+ Fragment" @default.
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- W2088502009 doi "https://doi.org/10.1002/chin.200051230" @default.
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