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- W2088509610 abstract "The hydrolysis of chlorosilanes R2SiCl2 (R = alkyl, aryl) is a well known reaction for preparing silanols and silanediols. With small alkyl groups the silanols and silanediols are unstable and condense spontaneously under formation of acyclic and cyclic siloxanes. Bulky organyl groups stabilize silanediols in such a manner that they do not condense, even under the influence of mineral acids or on heating in an autoclave. Analogous reaction behavior is found for other H-acidic silicon compounds such as aminosilanes, R3SiNH2 and R2Si(NH2)2, or silylphosphanes, R3SiPH2, and R2Si(PH2)2 This is in contrast to carbon chemistry, where compounds with two H-acidic groups bonded to the same carbon atom are unstable." @default.
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- W2088509610 date "2003-09-26" @default.
- W2088509610 modified "2023-09-23" @default.
- W2088509610 title "Functionalized Silanols and Silanolates" @default.
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- W2088509610 doi "https://doi.org/10.1002/9783527610761.ch25" @default.
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