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• W2088534996 abstract "The pure rotational spectra of three silicon isotopologues of HSiI and two isotopologues of DSiI have been recorded by pulsed-jet Fourier transform microwave (FTMW) spectroscopy. Neon was passed over dry ice cooled H3SiI or D3SiI and introduced into the pulsed valve of the FTMW spectrometer. The monoiodosilylenes HSiI and DSiI were produced in situ with a 1000 V DC-discharge nozzle. Only a-type transitions occur in monoiodosilylene from 6 to 26 GHz. We observe Ka = 0 a-type transitions for H28SiI, H29SiI, H30SiI, and D29SiI, and both Ka = 0 and 1 a-type transitions for D28SiI. Rotational constants, centrifugal distortion constants, iodine nuclear quadrupole coupling constants, and nuclear spin–molecular rotation constants were measured." @default.
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• W2088534996 date "2012-01-01" @default.
• W2088534996 modified "2023-09-27" @default.
• W2088534996 title "Fourier transform microwave spectroscopy of the reactive intermediate monoiodosilylene, HSiI and DSiI" @default.
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• W2088534996 doi "https://doi.org/10.1016/j.jms.2011.11.003" @default.
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