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- W2088561576 abstract "The mono-, di-, and trihydrates of nitric acid have been prepared as thin crystalline films and characterized by their distinctive infrared spectra. The infrared spectra of the mono- and trihydrates have been found to be significantly different than previously reported, to the extent that the published spectra are of questionable use. The spectrum of the dihydrate of HNO{sub 3}, which has not been reported previously, differs sharply from that of the other hydrates primarily because of effects indicative of a much more severely distorted nitrate ion. Infrared spectra are also reported for the tetra- and hexahydrate of HCl. The spectrum of the tetrahydrate largely duplicates existing data but is included for comparison with the previously unpublished spectrum of the hexahydrate. Sharp O-D stretching bands of dilute HOD in the hexahydrate are indicative of proton ordering within the network of the waters of hydrate and affirm the view based on x-ray data that, unlike the highest crystalline hydrate of HClO{sub 4}, the structure does not mimic that of the classical clathrate hydrates." @default.
- W2088561576 created "2016-06-24" @default.
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- W2088561576 date "1991-01-01" @default.
- W2088561576 modified "2023-10-14" @default.
- W2088561576 title "Infrared spectra of nitric and hydrochloric acid hydrate thin films" @default.
- W2088561576 doi "https://doi.org/10.1021/j100154a021" @default.
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